God, so hard to choose! What an outstanding season.So: cheating by having W/T and non-W/T categories, and by having more than one moment under a number if they occurred in the same scene
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W/T
1.W and T enjoying the party hanging out, playing pool etc., 5.6 Family
2.T supporting W at the end of 5.22 The Gift when W sees Buffy's body
3."She's my girl", 5.19 Tough Love
4.The Scoobies standing up for Tara in 5.6 Family
5.W and T snuggling, 5.6 Family
6.Willow telling Tara that she loves her ("even more"), 5.6 Family
7.The Kiss, 5.16 The Body
8.T reaching yearningly for W when W leaves to do the mindmeld with Buffy, 5.21 Weight of the World
9.W worriedly but gently pushing T away from Dawn when T reaches for Dawn, 5.20 Spiral
10.W and T holding hands and enjoying the flashback dinner, 5.16 The Body
Non-W/T
1.End of 5.7 Fool for Love, Spike deciding to try to comfort Buffy rather than kill her
2.Buffy running into the portal, 5.22 The Gift
Buffy's last words to Dawn and the montage, 5.22 The Gift
3.Anya's speech in 5.16 The Body
4.Buffy vomiting on the kitchen floor in 5.16 The Body
Buffy at the back door in 5.16 The Body
5.Buffy and the monk, 5.5 No Place Like Home, when Buffy finds out that Dawn doesn't know what she is
6.Dawn to Buffy, "Where'd she go?" at the end of 5.16 The Body
7.Dawn thanking Buffy, and Buffy close to breaking down, 5.20 Spiral
8.Buffy and Spike, last scene of 5.18 Intervention
9.Buffy and Dawn, 5.5 No Place Like Home, making up
10.Giles telling Buffy how proud he is of her, 5.20 Spiral
And also these ones:
Riley telling Xander in 5.3 The Replacement that Buffy doesn't love him
Joyce telling Buffy, "What would I do without you?" in 5.9 Listening To Fear before Joyce's surgery
Buffy and Angel kissing, 5.17 Forever
Buffy breaking down in front of Dawn in 5.17 Forever
Buffy finally revealing her real fears to Dawn, in 5.19 Tough Love